內容簡介

本書是作者《伏安法教程》的同步習題和解答,為學習伏安法的讀者在廣闊的理論和實驗背景上呈現了大量的習題並給出解答。本書的前幾章專注於熱動力學、電子輸運和擴散的基礎理論;緊接着是伏安測量實驗和分析,包括大量的宏觀和微觀伏安法的擴展問題;剩下的章節是有關對流、流體力學電極、均相動力學、吸附和電分析應用等。

Richard G. Compton(R.G.卡普頓,英國)是國際知名學者,在數學和物理學界享有盛譽。本書凝聚了作者多年科研和教學成果,適用於科研工作者、高校教師和研究生。
 

目錄

Publisher’’s Foreword
Glossary of Symbols and Abbreviations

1 Equilibrium Electrochenustry and the Nernst Equation
1.1 CeIIThermodynamics
1.2 TheNernstEquation
1.3 TheNernstEquation
1.4 TheNernstEquation
1.5 Theory ofthe Nernst Equation
1.6 The Debye-HuckeILimiting Law
1.7 CeIIReaction and Equilibrium Constant
1.8 CelIReaction and Equilibrium Constant
1.9 CelIReaction and Solubility Product
1.10 CeIIReaction andpKa
1.11 CeIIThermodynamics and Temperature
1.12 CellThermodynamics andTemperature
1.13 CeIIEnergetics
1.14 CeIIEMFandpH
1.15 CellReactionandEquilibria
1.16 CelIReaction and Kw
1.17 CeIIReaction and Disproportionation
1.18 FuelCelIEnergetics
1.19 FueICeUEnergetics
1.20 The Influence ofTemperature on the Self-Ionisation ofWater
1.21 CellReaction and Complexation
1.22 Reference Electrodes
1.23 FormalPotentials
1.24 FormaIPotentials
1.25 StandardPotentialsandpH
1.26 StandardPotentials andpH
1.27 Standard Potentials andpH

2 ElectrodeKinetics
2.1 Faraday’’s Laws ofElectrolysis
2.2 Electrodeposition
2.3 TafeIAnalysis: One-Electron Processes
2.4 TafelAnalysis:ElectrochemicallyReversibleProcesses
2.5 TafeIAnalysis:Mass Transport Correction
2.6 TafeIAnalysis:Two-Electron Processes
2.7 The Butler-Volmer Equation and the Nernst Equation
2.8 The Hydrogen Evolution Reaction
2.9 Requirement for Supporting Electrolyte
2.10 Frumkin Corrections
2.11 Marcus Theory and Standard Electrochemical Rate Constants
2.12 Marcus Theoryand Butler-Volmer Kinetics
2.13 Marcus Theory and the Role ofSolvent
2.14 Marcus Theory and thelnverted Region

3 Diffusion
3.1 Fick’’s LawsofDiffusion
3.2 Fick’’s Laws ofDiffusion
3.3 DiffusionDistances
3.4 TheCottrelIEquation
3.5 Derivation ofthe CottreIIEquation
3.6 Diffusion and Root-Mean-Square Displacement

4 CyclicVoltammetry at Macroelectrodes
4.1 CyclicVoltammetry: Electrochemically Reversible Voltammetry
4.2 CyclicVoltammetry:Electrochemicallylrreversible Voltammetry
4.3 ReversiblevsIrreversibleVoltammetry
4.4 VoltammetricDiagnostics
4.5 VoltammetryandScan RateEffects
……
5 Voltammetry at Microelectrodes
6 Voltammetry at Heterogeneous Surfaces
7 Cyclic Voltammetry: Coupled Homogeneous Kinetics and Adsorption
8 Hydrodynamic Electrodes
9 Voltammetry for Electroanalysis
10 Voltammetry in Weakly Supported Media: Migration and Other Effects
11 Voltammetry at the Nanoscale
Index
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